By Jin Rai Cho et al.
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I. Ugi, R. Meyr, U. Fetzer, C. Steinbru¨ckner, Angew. , 71, 386 (1959). 38. (a) I. Ugi, A. Do¨mling, W. Ho¨rl, Endeavour, 18, 115 (1994); (b) I. Ugi, A. Do¨mling, W. Ho¨rl, GIT Fachz. , 38, 430 (1994). 39. S. Mac Lane, G. Birkhoff, Algebra, Macmillan Company, New York, 1967, p. 3: Given sets of R and S have the intersection R > S with the common elements R and S. This means R > S ¼ fx j x , R and x , Sg, whereas a union R < S is R < S ¼ fx j x , R or x , Sg. 40. T. Yamada, Y. Omote, Y. Yamanaka, T.
10. A. Hantzsch, Liebigs Ann. , 219, 1 (1892); Ber. Dtsch. Chem. , 23, 1474 (1890); see also, C. Bo¨ttinger, Liebigs Ann. , 308, 122 (1981); U. Eisener, J. Kuthan, Chem. , 72, 1 (1972). 11. B. Radziszewski, Ber. Dtsch. Chem. , 15, 1499, 2706 (1882). 12. P. Biginelli, Ber. Dtsch. Chem. Ges. 24, 1317, 2962 (1891); 26, 447 (1893). 13. Bergs, H. German Patent No. 566094 (1929); Chem. Abstr. 27 1001 (1933); H. T. Bucherer, W. Steiner, J. Prakt. , 140, 291 (1934); H. T. Bucherer, H. Barsch, J. Prakt.
Being a six-carbon commodity graciously provided by Nature, albeit “overhydroxylated,” a full deoxygenation of glucose (or other hexoses) formally leads to n-hexane, which is usable as a liquid fuel. If such a process could be made practically feasible—this author is well aware that some will say “Never”—it would certainly exceed glucose-derived ethanol as a biofuel (additive), inasmuch as fermentation cuts the six-carbon chain into ethanol and CO2, while deoxygenation implies full atom economy by retaining it.
A Candidate of New Insensitive High Explosive by Jin Rai Cho et al.